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Prog. Theor. Phys. Vol. 53 No. 6 (1975) pp. 1566-1579
Order of the Phase Transition Related to the Interaction and the Degeneracy
Hizuo Nakano
Department of Applied Physics, Nagoya University, Nagoya
(Received September 20, 1974)
Abstract:
It is investigated how the order of phase transition in a system of
many identical interacting subsystems depends on the degeneracies of
the states of each subsystem and on the interaction between
subsystems; in particular, on the symmetry and uniformity of the
degeneracy and on the symmetry of the interaction. By denoting the
state of the i-th subsystem by a spin-like variable σi
(i = 1,2,…,N), the degeneracy is expressed as D(σi) as a
function of σi and the interaction between the i-th and
j-th subsystems as V(σi,σj). (In the text use is made
of such a normalized value as ΣσiD(σi) = 1). Then
the symmetry means the equalities D(σi) = D(-σi) and
V(σi,σj) = V(-σi,-σj) and the uniformity of
degeneracy means the independency of D(σi) upon
σi. The system of magnetic spins with exchange interactions
belongs to the uniform symmetric category, which is used as a
reference standard system in the present paper. The thermostatistical
average of σi which is denoted by σ represents the
order parameter in the system. Dependence of σ upon temperature
and some applied field are investigated to see the features of the
phase transition. In the non-uniform symmetric case it is found that
the phase transition of first order can occur for an adequate form of
D(σi), and that it is necessarily of second order in the
uniform symmetric case. The induced transition by the applied field is
also possible in the former case. In the asymmetric case the phase
transition of a peculiar type as well as the induced transition may
occur. Under some respective conditions on the degeneracy and
interaction parameters, transitions of first and second orders can
occur. Analytic properties of the partition functions are also
discussed. An exact problem is proposed for
the simplest model which is expected to exhibit the first-order phase
transition.
URL :
http://ptp.ipap.jp/link?PTP/53/1566/
DOI : 10.1143/PTP.53.1566
References:
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S. Strässler and C. Kittel, Phys. Rev. 139 (1965), A758[APS].
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C. N. Yang and T. D. Lee, Phys. Rev. 87 (1952), 404[APS].
T. D. Lee and C. N. Yang, Phys. Rev. 87 (1952), 410[APS].
- H. Nakano, Prog. Theor. Phys. 50 (1973), 1510[PTP].
see alo, S. Tanaka and S. Naya, Prog. Theor. Phys. 51 (1974), 1994[PTP].
O. J. Heilmann, Lett. Nuovo Cim. 3 (1972), 95.
- T. Hill, Proc. Natl. Acad. Sci. 58 (1967), 111; J. Chem. Phys. 20 (1952).
J. P. Changeux, J. Thiery, Y. Tung and C. Kittel, Proc. Natl. Acad. Sci. 57 (1967), 335.
- H. Nakano, Prog. Theor. Phys. 51 (1974), 1279[PTP].
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L. Onsager, Phys. Rev. 65 (1944), 117[APS].
C. N. Yang, Phys. Rev. 85 (1952), 808[APS].
For related papers see G. F. Newell and E. W. Montroll, Rev. Mod. Phys. 25 (1953), 353[APS].
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