Quick Search:
Prog. Theor. Phys. Supplement No.116 (1994) pp. 121-142
Semiclassical Approach to Few-Body Problems
— The Helium Atom
—
D. Wintgen,
A. Bürgers,
K. Richter and
G. Tanner
Fakultät für Physik, Universität Freiburg, Hermann-Herder-Str. 3, D-79104 Freiburg, Germany
Abstract:
We report on recent progress in the semiclassical description of two-electron atoms. We show that the classical dynamics for the helium atom is of mixed phase space structure, i.e. regular and chaotic motion coexists. Semiclassically, both types of motion require separate treatment. Stability islands are quantized via the Einstein-Brillouin-Keller torus-quantization procedure, whereas a periodic-orbit cycle expansion approach accounts for the state associated with hyperbolic electron pair motion. The results are compared with highly accurate ab initio quantum calculations, some of which are reported here for the first time.
URL :
http://ptp.ipap.jp/link?PTPS/116/121/
DOI : 10.1143/PTPS.116.121
References:
- M. S. Child, Semiclassical Mechanics with Molecular Applications (Clarendon, Oxford, 1991).
-
M. V. Berry and K. T. Mount, Rep. Prog. Phys. 35 (1972), 315[CrossRef].
- J. H. Van Vleck, Philos. Mag. 44 (1922), 842.
- M. C. Gutzwiller, Chaos in Classical and Quantum Mechanics (Springer, New York, 1990).
- M. Born, The Mechanics of the Atom (Ungar, New York, 1927).
-
J. G. Leopold and I. C. Percival, J. of Phys. B 13 (1980), 1037[IoP STACKS].
-
K. Richter and D. Wintgen, J. of Phys. B 23 (1990), L197[IoP STACKS].
-
K. Richter and D. Wintgen, Phys. Rev. Lett. 65 (1990), 1965[APS].
-
G. S. Ezra, K. Richter, G. Tanner and D. Wintgen, J. of Phys. B 24 (1991), L413[CrossRef].
- J.-H. Kim and G. S. Ezra, in Proc. Adriatico Conf. on Quantum Chaos, ed. H. Cerdeira et al. (World Scientific, Singapore, 1991).
- R. Blümel and W. P. Reinhardt, in Directions in Chaos, ed. B. L. Hao et al. (World Scientific, Hongkong, 1991), vol. 4.
- B. Eckhardt, Preprint Universität Marburg; Habilitationsschrift, Universität Marburg (1991).
-
J. Müller, J. Burgdörfer and D. W. Noid, Phys. Rev. A 45 (1992), 1471[APS].
-
P. Gaspard and S. A. Rice, Phys. Rev. A 48 (1993), 54[APS].
-
K. Richter, G. Tanner and D. Wintgen, Phys. Rev. A 48 (1993), 4182[APS].
- C. Marchal, The Three-Body Problem (Elsevier, Amsterdam, 1990).
- C. L. Siegel, Ann. Math. 42 (1941), 127.
-
H. M. James and A. S. Coolidge, Phys. Rev. 51 (1937), 857[APS].
-
G. Wannier, Phys. Rev. 90 (1953), 817[APS].
- O. Bohigas, S. Tomsovic and D. Ullmo, Phys. Rep. 223 (1993), 45.
-
M. Domke, C. Xue, A. Puschmann, T. Mandel, E. Hudson, D. A. Shirley, G. Kaindl, C. H. Greene, H. R. Sadeghpour and H. Petersen, Phys. Rev. Lett. 66 (1991), 1306[APS].
-
B. Eckhardt and D. Wintgen, J. of Phys. B 23 (1990), 355[IoP STACKS].
-
R. Schinke and V. Engel, J. Chem. Phys. 93 (1990), 3252[AIP Scitation].
-
P. Dahlqvist and G. Russberg, J. of Phys. A 24 (1991), 2736[IoP STACKS].
P. Dahlqvist, Chaos 2 (1992), 43.
-
D. Weiss, K. Richter, A. Menschig, R. Bergmann, H. Schweizer, K. von Klitzing and G. Weimann, Phys. Rev. Lett. 70 (1993), 4118[APS].
- M. Sieber and F. Steiner, Phys. Lett. A 148 (1990), 415.
M. Sieber, Dissertation, Univ. Hamburg (1991).
- G. Tanner and D. Wintgen, Chaos 2 (1992), 53.
-
P. Cvitanović and B. Eckhardt, Phys. Rev. Lett. 63 (1989), 823[APS].
-
B. Eckhardt and D. Wintgen, J. of Phys. A 24 (1991), 4335[IoP STACKS].
- R. McGehee, Inventiones Math. 27 (1974), 191.
- K. Richter, Dissertation, Univ. Freiburg (1991).
-
K. Richter and D. Wintgen, J. of Phys. B 24 (1991), L565[IoP STACKS].
K. Richter, J. S. Briggs, D. Wintgen and E. A. Solov'ev, J. of Phys. B 25 (1992), 3929[IoP STACKS].
-
Z. Zhem, Phys. Rev. A 41 (1990), 87[APS].
-
Y. K. Ho, Phys. Rep. 99 (1983), 1[CrossRef].
-
D. Wintgen and D. Delande, J. of Phys. B 26 (1993), L399[IoP STACKS].
-
M. C. Gutzwiller, J. Math. Phys. 8 (1967), 1979[CrossRef];
ibid. 10 (1969), 1004[CrossRef];
ibid. 11 (1970), 1791[CrossRef];
ibid. 12 (1971), 343[CrossRef].
-
M. J. Davies and E. J. Heller, J. Chem. Phys. 75 (1981), 246[AIP Scitation].
- D. Wintgen and K. Richter, Commun. At. Mol. Phys. 29 (1994), 261.
-
A. Voros, J. of Phys. A 21 (1988), 685[CrossRef].
-
R. Artuso, E. Aurell and P. Cvitanović, Nonlinearity 3 (1990), 325[IoP STACKS];
ibid. 3 (1990), 361[IoP STACKS].
- B. Eckhardt and E. Aurell, Europhys. Lett. 9 (1989), 509.
- A. Selberg, J. Ind. Math. Soc. 20 (1953), 47.
- J. Keating, Proceedings of the International School of Physics “Enrico Fermi”, Course CXIX, ed. G. Casati, I. Guarneri and U. Smilansky (North-Holland, Amsterdam, 1993), p. 147.
- D. Wintgen, K. Richter and G. Tanner, Chaos 2 (1992), 19.
-
B. Eckhardt and G. Russberg, Phys. Rev. E 47 (1993), 1578[APS].
- We put the weight of the orbit (+) to zero as this orbit is not really existent.
It describes an electron with zero kinetic energy infinitely far from the nucleus whereas the inner electron moves on degenerate Kepler ellipses, see, e.g. Ref. 15).
- H. Friedrich, Theoretical Atomic Physics (Springer, New York, 1992).
- U. Fano, Phys. Rep. 46 (1983), 97.
-
A. R. P. Rau, J. of Phys. B 16 (1983), L699[IoP STACKS].
-
S. Watanabe and C. D. Lin, Phys. Rev. A 34 (1986), 823[APS].
- A. Bürgers and D. Wintgen, to be published.