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Prog. Theor. Phys. Supplement No.116 (1994) pp. 179-205

[ Full Text PDF : FREE ACCESS (3025K) ]

Regular and Irregular Correspondences

— Adiabatic Invariants in Classical and Quantum Mechanics —

William P. Reinhardt

Department of Chemistry, BG-10, University of Washington, Seattle, WA 98112, U.S.A.

Abstract:

We outline a rather extraordinary series of similarities between classical and quantal behavior in the limit of adiabatic time changes. These include the power laws for the goodness of the respective invariants for isolated eigenstates and invariant tori for integrable systems, the nature of the breakdown of the invariances–level crossing in quantum systems and the role of ever present non-linear resonances is examined in the case of generically non-integrable classical dynamics–and the perhaps surprising relationship for fully chaotic systems where sufficiently slow switching in either classical or quantal systems precisely preserves the number of energy levels up to a given energy. For suitably small values of Planck's constant these similarities yield clear examples of the Bohr correspondence principle linking classical and quantum mechanics; for larger values the details in the classical picture are quenched in the quantum.


URL : http://ptp.ipap.jp/link?PTPS/116/179/
DOI : 10.1143/PTPS.116.179

[ Full Text PDF : FREE ACCESS (3025K) ] Citation:


References:

  1. A. Einstein, as quoted in M. Jammer, The Conceptual Development of Quantum Mechanics (McGraw Hill, 1966).
    Adiabaticity is discussed in pp. 89-108.
  2. P. Ehrenfest, Philos. Mag. 33 (1917), 500.
    If one substitutes “quantized” for “allowed” the sense of Ehrenfest's remark for quantization becomes apparent.
  3. M. Born and V. Fock, Z. Phys. 51 (1928), 165.
  4. L. Landau and E. M. Lifshitz, Quantum Mechanics (Non-Relativistic Theory) (Addison-Wesley, 1965), p. 142 et. Seq.
  5. M. Gell-Mann and F. E. Low, Phys. Rev. 84 (1951), 350[APS].
  6. L. Landau, Phys. Z. Sovietunion 2 (1932), 46.
    C. Zener, Proc. R. Soc. London A 137 (1933), 696.
  7. H. Eyring, J. Walter and G. E. Kimball, Quantum Chemistry (John Wiley, New York, 1944), p. 326.
    E. E. Nikitin, Theory of Elementary Atomic and Molecular Processes in Gases (Oxford, 1974), chap. 3.
  8. I. C. Percival, J. of Phys. B 6 (1973), L229[IoP STACKS].
  9. F. J. Sancho, Proc. Phys. Soc. London 89 (1966), 1.
  10. As was pointed out at the Kyoto Workshop by G. Schmidt, this is essentially a standard result of Fourier analysis: see, for example Tables of Integral Transforms, The Bataman Manuscript Project, ed. A. Erdelyi et al. (McGraw Hill, 1954), vol. 1, Table 1.3, p. 10.
  11. R. Abraham and J. E. Marsden, Foundations of Mechanics, 2nd Ed. (Benjamin/Cummings, Reading Mass. 1978).
  12. I. C. Percival, Adv. Chem. Phys. 36 (1977), 1.
    W. P. Reinhardt, Mathematical Analysis of Physical Systems, ed. R. E. Mickens (Van Nostrand, New York, 1985), p. 169.
  13. A. Einstein, Verh. d. D. Phys. Ges. 19 (1917), 82.
  14. P. Ehrenfest, Proc. Amsterdam Acad. 16 (1914), 591; ibid. 19 (1917), 576.
  15. M. Jammer, Ref. 1), p. 89.
  16. L. D. Landau and E. M. Lifshitz, Mechanics, 3rd ed. (Pergamon Press, 1976), p. 155.
  17. a) D. Noid, M. L. Koszykowski and R. Marcus, Ann. Rev. Phys. Chem. 32 (1981), 267.
    b) G. S. Ezra, C. C. Martens and L. E. Fried, J. Phys. Chem. 91 (1987), 372.
  18. E. A. Solov'ev, Sov. Phys. -JETP 48 (1978), 635.
  19. a) B. R. Johnson, J. Chem. Phys. 83 (1985), 1204.
    b) R. Skodje, F. Borondo and W. P. Reinhardt, J. Chem. Phys. 82 (1985), 4611.
    c) A review of adiabatic switching and semi-classical quantization is: W. P. Reinhardt, Adv. Chem. Phys. 73 (1989), 925.
    d) C. W. Patterson, J. Chem. Phys. 83 (1985), 4618.
  20. I. Dana and W. P. Reinhardt, Physica D 28 (1987), 115.
  21. E. Solov'ev, private communication (1988).
  22. F. R. Johnson and P. Pechukas, in The Physics of Phase Space, Lecture Notes in Phys. 278 (1987), 140.
    I. Dana and W. P. Reinhardt, ibid., p. 146.
  23. J. M. Burgers, Verslag van de Gewone Vergaderingen de Wis-en Natuurkundige Afdeeling Konieklijke Akedemie va Wetenschppente Amsterdam, 25, 848, 918, 1055 (1916).
  24. P. A. M. Dirac, Proc. R. Soc. London A 107 (1925), 725.
  25. H. Poincaré, Les Methods Nouvelles de la Machaniques Celeste (Gautier-Villars, Paris, 1892), p. 233.
  26. B. Chirikov, Phys. Rep. 52 (1979), 263[CrossRef].
  27. W. P. Reinhardt, in Collision Theory for Atoms and Molecules, NATO Adv. Study Series, vol. B196 (Physics), ed. F. A. Gianturko (Plenum, New York, 1989), p. 465.
  28. J. M. Greene, J. Math. Phys. 20 (1979), 1183[CrossRef].
  29. I. C. Percival, AIP Conf. Proc. 57 (1979), 302.
  30. M. V. Berry, AIP Conf. Proc. 46 (1978), 16.
  31. J. M. Greene and I. C. Percival, Physica D 3 (1981), 530.
  32. K. Husimi, Proc. Math.-Phys. Soc. Jpn. 22 (1940), 264.
  33. a) E. P. Wigner, Phys. Rev. 40 (1932), 749[APS].
    b) R. J. Glauber, Phys. Rev. 131 (1963), 202[APS].
  34. K. Takahashi, Prog. Theor. Phys. Suppl. No. 98 (1989), 109[PTP].
  35. K. Takahashi, J. Phys. Soc. Jpn. 55 (1986), 762[JPSJ]; ibid. 55 (1986), 1783[JPSJ].
    M. J. Davis, J. Phys. Chem. 92 (1988), 3124.
    R. L. Waterland, J-M. Yuan, C. C. Martens, R. E. Gillilan and W. P. Reinhardt, Phys. Rev. Lett. 61 (1988), 2733[APS].
    C. C. Martens, J. Chem. Phys. 90 (1989), 7064[AIP Scitation].
  36. M. Henon, Q. Appl. Math. 27 (1969), 291.
  37. S. Bleher and W. P. Reinhardt, Comments At. Mol. Phys. 25 (1990), 133.
  38. A review is G. Radons, T. Geisel and J. Rubner, Adv. Chem. Phys. 73 (1989), 891.
  39. S. Bleher and W. P. Reinhardt, unpublished work, 1991.
  40. S. Smale, the Mathematics of Time, Essays on Dynamical Systems, Economic Processes and Related Topics (Springer, New York, 1980).
  41. H. Kramers, Commun. Kamerlingh Onnes Lab 22, Suppl. 83 (1936), 1.
    N. Goldenfeld, Lectures on Phase Transitions and the Renormalization Group (Addison Wesley, Reading Mass, 1992), p. 80.
  42. S. Tomsovic and E. J. Heller, Phys. Rev. Lett. 67 (1991), 664[APS].
    M. Sepulevda, Thesis, University of Washington, August 1993; and presentations at the Yukawa Symposium.
  43. R. Kosloff and S. A. Rice, J. Chem. Phys. 74 (1981), 1340[AIP Scitation].
  44. P. Hertz, Ann. der Phys. 33 (1910), 225; ibid. 33 (1910), 537.
  45. P. Eherenfest, Philos. Mag. 33 (1917), 500.
  46. R. V. Lovelace, Phys. Fluids 22 (1979), 542[AIP Scitation].
  47. E. Ott, Phys. Rev. Lett. 42 (1979), 1628[APS].
  48. V. I. Arnold, Mathematical Methods of Classical Mechanics (Springer, New York, 1980).
  49. W. P. Reinhardt, J. Mol. Struct. 223 (1990), 157.
  50. M. Watanabe and W. P. Reinhardt, Phys. Rev. Lett. 26 (1990), 3301[APS].
  51. R. Brown, E. Ott and C. Grebogi, Phys. Rev. Lett. 59 (1987), 1173[APS].
    C. Jarzynski, Phys. Rev. Lett. 71 (1993), 839, [APS]has corrected and extended this analysis.
  52. A. Ramani, B. Dorizzi and B. Grammiticos, Phys. Rev. Lett. 49 (1982), 1539[APS].
  53. G. Bennetin, discussions at the Yukawa Symposium.
  54. W. P. Reinhardt and J. Hunter III, J. Chem. Phys. 97 (1992), 1599[AIP Scitation]; ibid. 99 (1993), 6856[AIP Scitation].
  55. G. Hogenson and W. P. Reinhardt, J. Chem. Phys. Lett. (submitted).