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Prog. Theor. Phys. Supplement No.12 (1959) pp. 183-210

[ Full Text PDF : FREE ACCESS (1874K) ]

Electronic Absorption Spectra of Molecular Crystals

Jiro Tanaka

The Institute for Solid State Physics, The University of Tokyo, Azabu-Shinryudo-cho, Minato-ku, Tokyo

Abstract:

Electronic absorption spectra of aromatic molecular crystals are reviewed from theoretical and experimental points of view. A theory of molecular exciton proposed by Davydov is described with some particular examples. A theory of electron transfer in molecular crystal is discussed in connection with the mechanism of photoconduction, and other theories relevant to optical properties of insulating crystals are briefly surveyed.
Experimental results on the electronic absorption spectra of molecular crystals are presented classifying the molecules into three classes; namely, benzene and its derivatives, catacondensed aromatic hydrocarbons, and other miscellaneous molecules. It is emphasized that the measurements of the spectra of molecular crystals give valuable information on the excited states of these molecules as well as on the behaviour of exciton in these crystals.


URL : http://ptp.ipap.jp/link?PTPS/12/183/
DOI : 10.1143/PTPS.12.183

[ Full Text PDF : FREE ACCESS (1874K) ] Citation:


References:

  1. R. G. Parr and F. O. Ellison, Ann. Rev. Phys. Chem. 6 (1955), 171.
  2. H. C. Longuet-Higgins, Adv. Chem. Phys. 1 (1958), 239.
  3. J. Tanaka, J. Chem. Soc. Jpn. 78 (1957), 1636; ibid. 79 (1958), 1114 (in Japanese).
  4. A. S. Davydov, J. Exp. Theor. Phys. (USSR) 18 (1948), 210.
  5. D. P. Craig, Rev. Pure Appl. Chem. (Australia). 3 (1953), 207.
  6. J. Frenkel, Phys. Rev. 37 (1931), 17[APS]; ibid. 37 (1931), 1276[APS].
    R. Peierls, Ann. der Phys. 405 (1932), 905.
  7. F. Seitz, The Modern Theory of Solids p. 414, McGraw-Hill (1940), New York.
  8. W. R. Heller and A. Marcus, Phys. Rev. 84 (1951), 809[APS].
  9. D. P. Craig and P. C. Hobbins, J. Chem. Soc. (1955), 539.
  10. D. P. Craig, J. Chem. Soc. (1955), 2302.
  11. D. Fox and O. Schnepp, J. Chem. Phys. 23 (1955), 767[AIP Scitation].
  12. H. Winston and R. S. Halford, J. Chem. Phys. 17 (1949), 607[AIP Scitation].
  13. H. Winston, J. Chem. Phys. 19 (1951), 156[AIP Scitation].
  14. H. Eyring, J. Walter and G. E. Kimball, Quantum Chemistry, John Wiley and Sons, (1944), New York.
  15. A. McL. Mathieson, J. M. Robertson and V. C. Sinclair, Acta. Cryst. 3 (1950), 245.
    D. W. J. Cruickshank, Acta Cryst. 9 (1956), 915.
  16. D. Fox and S. Yatsiv, J. Chem. Phys. 24 (1956), 1103[AIP Scitation].
  17. D. Fox and S. Yatsiv, Phys. Rev. 108 (1957), 938[APS].
  18. D. P. Craig and J. R. Walsh, J. Chem. Phys. 25 (1956), 588[AIP Scitation].
  19. D. P. Craig and J. R. Walsh, J. Chem. Phys. (1958), 1613.
  20. W. T. Simpson and D. L. Peterson, J. Chem. Phys. 26 (1957), 588[AIP Scitation].
  21. D. S. McClure, Can. J. Chem. 36 (1958), 59.
  22. A. S. Davydov, J. Exp. Theor. Phys. (USSR) 21 (1951), 673.
  23. D. S. McClure and O. Schnepp, J. Chem. Phys. 23 (1955), 1575[AIP Scitation].
  24. J. N. Ferguson, J. Chem. Phys. 28 (1958), 765[AIP Scitation].
  25. L. E. Lyons, J. Chem. Soc. (1958), 1347.
  26. J. Tanaka, J. Chem. Soc. Jpn. 79 (1958), 1373 (in Japanese).
  27. D. L. Peterson and W. T. Simpson, J. Am. Chem. Soc. 78 (1957), 2375.
  28. J. C. D. Brand and T. H. Goodwin, Trans. Faraday Soc. 53 (1957), 295.
  29. F. Seitz, Ref. 7), p. 468.
  30. L. E. Lyons, J. Chem. Soc. (1957), 5001.
  31. H. Sponer, Y. Kanda and L. A. Blackwell, J. Chem. Phys. 29 (1958), 721[AIP Scitation].
  32. N. W. Blake and D. S. McClure, J. Chem. Phys. 29 (1958), 722[AIP Scitation].
  33. J. C. Slater and W. Schockley, Phys. Rev. 50 (1936), 705[APS].
  34. M. Kasha and S. P. McGlynn, Ann. Rev. Phys. Chem. 7 (1956), 403.
  35. B. Rosenberg, J. Chem. Phys. 29 (1958), 1108[AIP Scitation].
  36. M. Lax, J. Chem. Phys. 20 (1952), 1752[AIP Scitation].
  37. G. Dresselhaus, Phys. Rev. 106 (1957), 76[APS].
  38. R. J. Elliot, Phys. Rev. 108 (1957), 1384[APS].
  39. J. Kommandeur, G. J. Korniek and W. G. Schneider, Can. J. Chem. 36 (1958), 607.
  40. J. Kommandeur, G. J. Korniek and W. G. Schneider, Can. J. Chem. 35 (1957), 998.
  41. D. P. Craig, Proc. R. Soc. (London) A 200 (1950), 474.
  42. R. G. Parr, D. P. Craig and I. G. Ross, J. Chem. Phys. 18 (1950), 1561[CrossRef].
  43. M. Goeppert-Mayer and A. L. Sklar, J. Chem. Phys. 6 (1938), 645[CrossRef].
  44. H. Sponer, G. Nordhein, A. L. Sklar and E. Teller, J. Chem. Phys. 7 (1939), 207[CrossRef].
  45. L. Broude, V. S. Medvedev and A. F. Prikhotjko, J. Exp. Theor. Phys. 21 (1951), 665.
  46. E. P. Carr and H. Stücklen, J. Chem. Phys. 7 (1939), 631[AIP Scitation].
  47. V. J. Hammond, W. C. Price, J. P. Teegan and A. D. Walsh, Discussions Faraday Soc. 9 (1950), 53.
  48. G. Scheibe, St. Hartwig and R. Müller, Z. Elektrochem. 49 (1943), 372.
  49. D. P. Craig and L. E. Lyons, Nature 169 (1952), 1102.
  50. R. C. Nelson and W. T. Simpson, J. Chem. Phys. 23 (1955), 1146[AIP Scitation].
  51. V. J. Hammond and W. C. Price, Trans. Faraday Soc. 51 (1955), 605.
  52. J. Romand and B. Vodar, Compt. rend. 233 (1951), 930.
  53. A. C. Albrecht and W. T. Simpson, J. Chem. Phys. 23 (1955), 1480[AIP Scitation].
  54. O. Schnepp and D. S. McClure, J. Chem. Phys. 26 (1957), 83[AIP Scitation].
  55. R. Coffman and D. S. McClure, Can. J. Chem. 36 (1958), 48.
  56. O. Schnepp and D. S. McClure, J. Chem. Phys. 30 (1959), 874[AIP Scitation].
  57. O. Schnepp and R. Kopelman, J. Chem. Phys. 30 (1959), 868[AIP Scitation].
  58. O. Schnepp, J. Chem. Phys. 30 (1959), 863[AIP Scitation].
  59. S. Nagakura and J. Tanaka, J. Chem. Phys. 22 (1954), 236[AIP Scitation].
    S. Nagakura, J. Chem. Phys. 23 (1955), 1441[AIP Scitation].
  60. J. Tanaka, S. Nagakura and M. Kobayashi, J. Chem. Phys. 24 (1956), 311[AIP Scitation].
    J. Tanaka and S. Nagakura, J. Chem. Phys. 24 (1956), 1274[AIP Scitation].
  61. J. Tanaka, J. Chem. Soc. Jpn. 79 (1958), 1373 (in Japanese).
  62. S. C. Abrahams and J. M. Robertson, Acta Cryst. 1 (1948), 252.
  63. I. Donochue and K. N. Trueblood, Acta Cryst. 9 (1956), 960.
  64. J. N. Murrell, Proc. Phys. Soc. A 68 (1955), 969.
  65. J. Tanaka, J. Chem. Soc. Jpn. 79 (1958) 1379 (in Japanese).
  66. E. Clar, Aromatische Kohlenwasserstoffe, Julius Springer, Berlin (1952).
  67. H. B. Klevens and J. R. Platt, J. Chem. Phys. 17 (1947), 470[CrossRef].
  68. C. A. Coulson, Proc. Phys. Soc. A 60 (1948), 257.
  69. J. R. Platt, J. Chem. Phys. 17 (1949), 484[CrossRef].
  70. J. S. Ham and K. Rudenberg, J. Chem. Phys. 25 (1956), 13[CrossRef].
  71. W. Moffitt, J. Chem. Phys. 22 (1954), 320[CrossRef]; ibid. 22 (1954), 1820[CrossRef].
  72. R. Pariser and R. G. Parr, J. Chem. Phys. 21 (1953), 466[CrossRef]; ibid. 21 (1953), 767[CrossRef].
  73. R. Parisser, J. Chem. Phys. 24 (1956) 250[CrossRef]; ibid. 25 (1956), 1112[AIP Scitation].
  74. M. J. S. Dewar and H. C. Longuet-Higgins, Proc. Phys. Soc. A 67 (1954), 795.
  75. J. A. Pople, Proc. Phys. Soc. A 68 (1955), 81.
  76. O. Schnepp and D. S. McClure, J. Chem. Phys. 21 (1953), 959[AIP Scitation].
  77. D. P. Craig and L. E. Lyons, J. Chem. Phys. 20 (1952), 1499[AIP Scitation].
  78. D. S. McClure, J. Chem. Phys. 22 (1954), 1668[AIP Scitation].
  79. A. Prikohtjko, J. Exp. Theor. Phys. 19 (1949), 383.
  80. J. Sidman and D. S. McClure, J. Chem. Phys. 24 (1955), 757[AIP Scitation].
  81. E. Clar, Spectrochim. Acta, 4 (1950), 116.
  82. J. Ferguson, L. W. Reeves and W. G. Schneider, Can. J. Chem. 35 (1957), 1117.
  83. A. V. Bree and L. E. Lyons, J. Chem. Soc. (1956), 2662.
  84. J. Sidman, J. Chem. Phys. 25 (1956), 115[AIP Scitation].
  85. D. P. Craig and P. C. Hobbins, J. Chem. Soc. (1955), 2309.
  86. J. Sidman, Phys. Rev. 102 (1956), 96[APS].
  87. J. Ferguson and W. G. Schneider, J. Chem. Phys. 28 (1958), 761[AIP Scitation].
  88. D. M. J. Compton, W. G. Schneider and T. C. Waddington, J. Chem. Phys. 27 (1957), 160[AIP Scitation].
  89. L. E. Lyons and G. C. Morris, J. Chem. Soc. (1959), 1551.
  90. D. S. McClure, J. Chem. Phys. 25 (1956), 481[AIP Scitation].
  91. J. Sidman, J. Chem. Phys. 25 (1956), 122[AIP Scitation].
  92. J. Tanaka, to be published.
  93. W. Moffitt, J. Chem. Phys. 25 (1956), 467[CrossRef]; Proc. Natl. Acad. Sci. 42 (1956), 736.
  94. K. Imahori and J. Tanaka, J. Molecular Biology, (1959).
  95. J. Sidman, J. Am. Chem. Soc. 77 (1955), 6461; ibid. 77 (1955), 6471; ibid. 78 (1956), 2363; ibid. 78 (1956), 4567.
  96. J. Sidman, Chem. Revs. 58 (1958), 689.
  97. R. S. Mulliken, J. Am. Chem. Soc. 74 (1952), 811[CrossRef]; J. Phys. Chem. 56 (1952), 801.
  98. K. Nakamoto, J. Am. Chem. Soc. 74 (1952), 1739.
  99. D. S. McClure, Solid State Phys. 8 (1958), 1.
  100. H. C. Wolf, Solid State Phys. 9 (1959), 1.